<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Burda, Clemens</style></author><author><style face="normal" font="default" size="100%">El-Sayed, Mostafa A</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">High-density femtosecond transient absorption spectroscopy of semiconductor nanoparticles. A tool to investigate surface quality</style></title><secondary-title><style face="normal" font="default" size="100%">Pure and Applied Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2000</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Jan-Feb</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1-2</style></number><volume><style face="normal" font="default" size="100%">72</style></volume><pages><style face="normal" font="default" size="100%">165-177</style></pages><isbn><style face="normal" font="default" size="100%">0033-4545</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">At the high laser excitation intensities used in our experiments, more than 50 electron-hole pairs are formed in colloidal semiconductor nanoparticles used in our studies. At this density of charge carriers, new transient absorptions are observed in the femtosecond transient spectra in the 450 to 700 nm region with unresolved fast rise (&lt;100 fs) and two decay components of 660 fs and &gt;150 ps. The absorption at 510 nm could be quenched with the adsorption of electron accepters (e.g., benzoquinone, 1,2-naphthoquinone), whereas the low-energy transient absorption was not affected. For CdS NPs, we found that passivation eliminated most of the transient absorption. The transient absorptions are thus proposed to result from either trap-state absorption, trapped dimers (or complexes) and/or Stark-shifted exciton absorption resulting from surface electric field of the uncompensated trapped electron-hole pairs. All these possibilities require effective surface trapping at these high levels of excitation.</style></abstract><accession-num><style face="normal" font="default" size="100%">WOS:000087833100019</style></accession-num><notes><style face="normal" font="default" size="100%">Burda, C El-Sayed, MA1st IUPAC Workshop on Advanced Material (WAM1)Jul 14-18, 1999Hong kong, peoples r chinaIupac</style></notes><electronic-resource-num><style face="normal" font="default" size="100%">10.1351/pac200072010165</style></electronic-resource-num></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Link, Stephan</style></author><author><style face="normal" font="default" size="100%">Burda, Clemens</style></author><author><style face="normal" font="default" size="100%">Nikoobakht, Babak</style></author><author><style face="normal" font="default" size="100%">El-Sayed, Mostafa A</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">How long does it take to melt a gold nanorod? A femtosecond pump-probe absorption spectroscopic study</style></title><secondary-title><style face="normal" font="default" size="100%">Chemical Physics Letters</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">1999</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Dec</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1-2</style></number><volume><style face="normal" font="default" size="100%">315</style></volume><pages><style face="normal" font="default" size="100%">12-18</style></pages><isbn><style face="normal" font="default" size="100%">0009-2614</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Using pump-probe femtosecond transient absorption spectroscopy, we determined the rate of the bleach of absorption around 700-800 nm due to the longitudinal surface plasmon band of gold nanorods. Using TEM of the spotted, completely irradiated solutions suggest that the dominant products of the photothermal conformation of the rods are spheres of comparable volume. This lead to the conclusion that the melting of the rods is at least 30-35 ps, independent of the power used (5-20 mu J) or the nanorod aspect ratio (1.9-3.7). (C) 1999 Elsevier Science B.V. All rights reserved.</style></abstract><accession-num><style face="normal" font="default" size="100%">WOS:000084321900003</style></accession-num><notes><style face="normal" font="default" size="100%">Link, S Burda, C Nikoobakht, B El-Sayed, MA</style></notes><electronic-resource-num><style face="normal" font="default" size="100%">10.1016/s0009-2614(99)01214-2</style></electronic-resource-num></record></records></xml>