Enhanced Photoassisted Water Electrolysis Using Vertically Oriented Anodically Fabricated Ti-Nb-Zr-O Mixed Oxide Nanotube Arrays

TitleEnhanced Photoassisted Water Electrolysis Using Vertically Oriented Anodically Fabricated Ti-Nb-Zr-O Mixed Oxide Nanotube Arrays
Publication TypeJournal Article
Year of Publication2010
AuthorsAllam, NK, Alamgir, F, EL-Sayed, MA
JournalAcs Nano
Volume4
Pagination5819-5826
Date PublishedOct
ISBN Number1936-0851
Accession NumberWOS:000283453700046
Abstract

Self-ordered, highly oriented arrays of titanium-niobium-zirconium mixed oxide nanotube films were fabricated by the anodization of Ti(35)Nb(5)Zr alloy in aqueous and formamide electrolytes containing NH(4)F at room temperature. The nanostructure topology was found to depend on the nature of the electrolyte and the applied voltage. Our results demonstrate the possibility to grow mixed oxide nanotube array films possessing several-micrometer-thick layers by a simple and straightforward electrochemical route. The fabricated Ti-Nb-Zr-O nanotubes showed a similar to 17.5% increase in the photoelectrochemical water oxidation efficiency as compared to that measured for pure TiO(2) nanotubes under UV illumination (100 mW/cm(2), 320-400 nm, 1 M KOH). This enhancement could be related to a combination of the effect of the thin wall of the fabricated Ti-Nb-Zr-O nanotubes (10 +/- 2 nm) and the formation of Zr oxide and Nb oxide layers on the nanotube surface, which seems to slow down the electron-hole recombination in a way similar to that reported for Gratzel solar cells.

DOI10.1021/nn101678n